Basically, a salt based water softener works to remove high concentrations of calcium and magnesium from water through a process called “ion exchange.” This process “softens” hard water by substituting the hardness minerals (calcium and magnesium) with sodium chloride (salt).
Temporary hardness:
1. Ca(HCO3)2 + Ca(OH)2 → 2CaCO3 ↓ +2H2O
2. Mg(HCO3)2 + 2Ca(OH)2 → 2MgCO3 +2H2O
3. MgCO3 + Ca(OH)2 → Mg(OH)2 + CaCO3
Permanent Hardness:
- CaSO4 + Na2CO3 → CaCO3+ Na2SO4
- MgSO4 + Na2CO3 → MgCO3+ Na2SO4
- MgCO3 + Ca(OH)2 → Mg(OH)2 + CaCO3
To remove temporary hardness we need to boil the hard water but permanent hardness cannot be removed by boiling but can often be
removed by chemical treatment